For a long time, my collection of Physics problems has been one of the largest draws on my website. Now, many of my favorite graduate Physics problems are available in an e-book from Bitingduck Press, Truly Tricky Graduate Physics Problems.
The solutions that have previously been available here are still available for free, and always will be. I find them helpful as a reference and wanted them to be available to others as well. The solutions in the book include my own favorite problems as well as new problems from the other authors, Jay Nadeau and Leila Cohen, and are written in a format that can easily be cut-and-pasted into your favorite computer algebra system.
If you've found my Physics problem collection helpful in preparing for your qualifying exams, you may want to check out the e-book as well for more challenging Physics problems to help you prepare.
Sunday, December 1, 2013
Sunday, November 17, 2013
Pinhole Picture from Arizona
Last January, I hid 5 pinhole cameras in the desert near Phoenix, AZ with the goal of taking some stunning pinhole photographs, taking advantage of the bright desert sun and the reflective desert sand. In order to ensure that they wouldn't be found, we pulled over at a random place along N. Bush Highway, walked about 50 feet in the desert, and plastic tied the cameras to stumps or desert flora.
I still think it was a pretty solid plan, but there were a few flaws. First, the desert in Arizona gets so hot that even the photo paper doesn't want to deal with it. It looks like after only a month or two of hot days, the photo paper curled up in the oven-like can and completely stopped exposing. Second, my estimation of how much light reflects off the sand was pretty far off. The parts of the image that looked at sand were just dark and indistinct. The simple fact is that the sun is so bright that everything else may as well be black. Third, it turns out that the desert there must see more pedestrian traffic than I expected. One of my cameras was totally destroyed, and one had been torn open and the photo paper taken out.
The one shot that came out all right was less than ideal. I had placed the can horizontally and facing East on the theory that I would get reflections of the sunrise off of the desert sand, and that the sunrises over Four Peaks would give a striking horizon. I guess it sort of worked, except that the desert was nothing distinct and Four Peaks was partially obscured by some desert plants.
I still think it was a pretty solid plan, but there were a few flaws. First, the desert in Arizona gets so hot that even the photo paper doesn't want to deal with it. It looks like after only a month or two of hot days, the photo paper curled up in the oven-like can and completely stopped exposing. Second, my estimation of how much light reflects off the sand was pretty far off. The parts of the image that looked at sand were just dark and indistinct. The simple fact is that the sun is so bright that everything else may as well be black. Third, it turns out that the desert there must see more pedestrian traffic than I expected. One of my cameras was totally destroyed, and one had been torn open and the photo paper taken out.
The one shot that came out all right was less than ideal. I had placed the can horizontally and facing East on the theory that I would get reflections of the sunrise off of the desert sand, and that the sunrises over Four Peaks would give a striking horizon. I guess it sort of worked, except that the desert was nothing distinct and Four Peaks was partially obscured by some desert plants.
Monday, November 11, 2013
Diminishing Returns in the Game of Go
We've been playing a lot of Go at work lately. Sometimes my mind wanders as I play, and I see parallels to life in the board positions. Arguments, negotiations, trades, consensus, squabbling, greed and fear.
The goal of Go is to surround as much territory using your stones as possible. So, if at all possible, players should try to place stones in such a way as to grab the most area first, and then leave small amounts of area, just a few points, for last. The game ends either when one player surrenders or when both players feel that the remaining moves are worth zero points or less. I wonder: what does the rate of diminishing returns look like in Go? How much is the first move worth versus the second? The tenth? the hundredth? Knowing this will help me understand when it might be worth it to walk away from a battle versus to keep fighting it at each stage of the game.
As a secondary goal, I'd like to evaluate komi. Komi is an amount of points granted to the white player to offset the disadvantage of going second. Ideally, the komi should be set such that if both players played perfectly, then black's score would exactly equal white's score. If Go is to be a fair game, then if I assigned each move m a point value V(m) and that black and white took turns making M moves in a game without passing, I would expect that
I will use GNU Go and the Go Text Protocol to evaluate a freely available collection of Go games from Andries Brouwer, and also to generate a set of computer games where GNU Go plays itself. After each move, I will ask GNU Go to run evaluate_score and see how the score has changed from the previous move. I posit that this difference is an estimate for V(m) in the equation above.
I used this python script to generate the simulated games. I then produced a box and whisker plot for the calculated V(m) for each move using the following bash commands:
Plotting using xmgrace tells a pretty cool story:
There are several important messages to take from Figure 1. First, as demonstrated by the narrow interquartile range shown in blue, that typical moves in Go have a value that is closely related to the move number. Second, we see that Go is also a game of tactics where particular tactical situations can be responsible for wild fluctuations in the score. Very good tactical moves account for the extreme high move values, and very poor moves account for the extreme low move values. This plot also underscores the point of my study: when it is a good idea to simply walk away from a battle and play elsewhere. Clearly, if I believe that a battle is worth 20 or more points, I should always fight it according to this plot. Below that, the story becomes more interesting.
Figure 2 shows a different view of the simulated data in Figure 1. The interquartile range shows the values of typical moves in Go. The median value of the first move of the game is 10.4 points. The median value of the tenth is 7.3, the fiftieth is 4.9, the hundredth is 2.8, and the hundred-fiftieth is 1.3. These figures give me an idea of the immediate value of sente, or when it may be worthwhile to simply ignore the opponent's last move and play elsewhere.
Next, I wonder if Equation 1 allows me to reconstruct Komi. A simple command line allows me to perform the calculation:
This estimate is not even close to GNU Go's default Komi, 5.5. This reveals a limitation of my study: while most moves' values fall in a narrow interquartile range, no game is composed entirely of typical moves shown in Figure 2. Victory lies not in these average moves, but instead in the long tail of outliers visible in Figure 1 (green extremes).
Now let's try this experiment again with 5000 human games. I will start with the empty board, then after each turn ask GNU Go to evaluate the new value of the board. The difference between the previous board value and the next will be called the value of each move.
Figure 3 looks vaguely reminiscent of Figure 1, but with a glaring difference: the value of the moves in the mid-game actually seems to be greater than the value of the early game moves! Let's take a closer look at this by focusing on the interquartile range.
Comparing Figure 4 to Figure 2, it becomes clear that there is something profoundly different between the human games and the AI games. The GNU Go-predicted point value of moves remains high, around 10 stones on average, out to the hundredth move. Further, the interquartile range is much broader and skewed towards more valuable moves. So, what's going on here?
First, consider that most of the human games end in resignation. None of the GNU Go games end in resignation. So, what do human players do when they feel that they are losing lost that GNU Go does not? They try a hail Mary. They make an exceptionally risky move that, while likely to fail, may put them back in the game. If this risk fails, a human player will probably resign.
Figure 5 shows us that human games tend to be shorter than GNU Go games due to resignation, and taken together with figures 3 and 4 we see that the losing player tends to make big gambles that are worth a lot of points if they succeed. AI players, on the other hand, cannot transcend their heuristic algorithm. They will make the move that they see as most profitable every time, whether they are ahead or behind.
Finally, I want to discuss exactly what the value of a move means. Above, I have posited that the value of a move is the point value, in stones. But, what if you don't care about points, and only care about winning or losing by any number of points? The one point that puts you slightly ahead of your opponent, then, is worth more than 50 points that still leave you behind.
This is a difference between the Pachi algorithm and GNU Go. GNU Go is concerned about values in stones, and Pachi is concerned about probability of winning. Pachi, in fact, will resign if it cannot find any scenario in which it will win. Pachi's Monte Carlo algorithm was a huge breakthrough in computer Go, but its skill on a 19 by 19 board is still a far cry from professional play. A fun experiment is to use the sgf-analyze.pl script included with Pachi to track probability of winning through a game, and as such to identify the major plays and blunders of a game.
Pachi supposedly plays at a 2d level on KGS, which means that it is likely to have a hard time analyzing games by players at a higher level than 2d.
Out of curiosity, I tried runing sgf-analyze on a 9d game annotated by GoGameGuru. I ran 1 million simulations per move using the extra pattern files, and ran analyze-sgf once for black and once for white. The output of sgf-analyze looks something like this:
Sample output from Pachi's sgf-analyze.pl script.
The output from sgf-analyze is easy to work with. I used a procedure like this to generate the beautiful plot in Figure 6.
The first column is the move, the second column is the player color, the third is the move actually played, the fourth is the suggested move by Pachi, and the fifth column is the probability (according to Pachi) of this player winning assuming that he plays the recommended move. There is no doubt that these 9d players are much better than Pachi, so I'll assume that their moves are at least as good as the recommended one, and that this probability equals their probability of winning at the end of this move.
Like GNU Go, Pachi is only as good as its heuristic algorithm, and if it can't see as far ahead in the game as the professionals can, then the probability it predicts will not be illuminating. Indeed, comparing the GoGameGuru's notes on which moves were brilliant and which were mistakes to Pachi's did not yield any noticeable correlation. In fact, Pachi seemed to think that black resigned when he was in fact coming back!
Pachi's analysis of the 9d game is understandably flawed, as it is not as strong as these players. Still, the analysis by Pachi shows an important point: the value of a move depends greatly on your definition of value. If you care about expected point value then, indeed, an early game move is much more valuable than a late game move. On the other hand, if you care about winning or losing then the game can certainly come down to a matter of a few points, and those few points can make a world of difference regardless of when they are secured. The professional game analyzed in Figure 6 changed hands no fewer than three times: twice in the mid-game, and once again at the end. If I had a lot of spare processor cycles, it would be interesting to perform this analysis with Pachi on a large number of games and explore the distribution of points where the lead player changes hands.
This analysis may have raised more questions than answers, but I did learn a few things about computer Go and human nature:
The goal of Go is to surround as much territory using your stones as possible. So, if at all possible, players should try to place stones in such a way as to grab the most area first, and then leave small amounts of area, just a few points, for last. The game ends either when one player surrenders or when both players feel that the remaining moves are worth zero points or less. I wonder: what does the rate of diminishing returns look like in Go? How much is the first move worth versus the second? The tenth? the hundredth? Knowing this will help me understand when it might be worth it to walk away from a battle versus to keep fighting it at each stage of the game.
As a secondary goal, I'd like to evaluate komi. Komi is an amount of points granted to the white player to offset the disadvantage of going second. Ideally, the komi should be set such that if both players played perfectly, then black's score would exactly equal white's score. If Go is to be a fair game, then if I assigned each move m a point value V(m) and that black and white took turns making M moves in a game without passing, I would expect that
![]() |
| Equation 1: Calculation of komi using V(m), the point value of the m-th move in a game of Go. M is the number of moves in an ideal, perfect game, and it is assumed that no player pass during play. |
I will use GNU Go and the Go Text Protocol to evaluate a freely available collection of Go games from Andries Brouwer, and also to generate a set of computer games where GNU Go plays itself. After each move, I will ask GNU Go to run evaluate_score and see how the score has changed from the previous move. I posit that this difference is an estimate for V(m) in the equation above.
I used this python script to generate the simulated games. I then produced a box and whisker plot for the calculated V(m) for each move using the following bash commands:
# Get all deltas.
# Produce box and whisker plots for each move. |
Plotting using xmgrace tells a pretty cool story:
![]() |
| Figure 1: Value of moves in go V(m) calculated using 5000 games simulated by GNU Go on a 19 by 19 board. Score estimates come from GNU Go's built in estimate_score function. |
Figure 2 shows a different view of the simulated data in Figure 1. The interquartile range shows the values of typical moves in Go. The median value of the first move of the game is 10.4 points. The median value of the tenth is 7.3, the fiftieth is 4.9, the hundredth is 2.8, and the hundred-fiftieth is 1.3. These figures give me an idea of the immediate value of sente, or when it may be worthwhile to simply ignore the opponent's last move and play elsewhere.
Next, I wonder if Equation 1 allows me to reconstruct Komi. A simple command line allows me to perform the calculation:
cat simulated-box-and-whisker | awk '{print $4}' | awk 'BEGIN {t=0} (NR % 2 == 0) {t -= $1} (NR % 2 == 1) {t += $1} END {print t}' |
This estimate is not even close to GNU Go's default Komi, 5.5. This reveals a limitation of my study: while most moves' values fall in a narrow interquartile range, no game is composed entirely of typical moves shown in Figure 2. Victory lies not in these average moves, but instead in the long tail of outliers visible in Figure 1 (green extremes).
Now let's try this experiment again with 5000 human games. I will start with the empty board, then after each turn ask GNU Go to evaluate the new value of the board. The difference between the previous board value and the next will be called the value of each move.
![]() | |
|
Comparing Figure 4 to Figure 2, it becomes clear that there is something profoundly different between the human games and the AI games. The GNU Go-predicted point value of moves remains high, around 10 stones on average, out to the hundredth move. Further, the interquartile range is much broader and skewed towards more valuable moves. So, what's going on here?
First, consider that most of the human games end in resignation. None of the GNU Go games end in resignation. So, what do human players do when they feel that they are losing lost that GNU Go does not? They try a hail Mary. They make an exceptionally risky move that, while likely to fail, may put them back in the game. If this risk fails, a human player will probably resign.
Figure 5 shows us that human games tend to be shorter than GNU Go games due to resignation, and taken together with figures 3 and 4 we see that the losing player tends to make big gambles that are worth a lot of points if they succeed. AI players, on the other hand, cannot transcend their heuristic algorithm. They will make the move that they see as most profitable every time, whether they are ahead or behind.
Finally, I want to discuss exactly what the value of a move means. Above, I have posited that the value of a move is the point value, in stones. But, what if you don't care about points, and only care about winning or losing by any number of points? The one point that puts you slightly ahead of your opponent, then, is worth more than 50 points that still leave you behind.
This is a difference between the Pachi algorithm and GNU Go. GNU Go is concerned about values in stones, and Pachi is concerned about probability of winning. Pachi, in fact, will resign if it cannot find any scenario in which it will win. Pachi's Monte Carlo algorithm was a huge breakthrough in computer Go, but its skill on a 19 by 19 board is still a far cry from professional play. A fun experiment is to use the sgf-analyze.pl script included with Pachi to track probability of winning through a game, and as such to identify the major plays and blunders of a game.
Pachi supposedly plays at a 2d level on KGS, which means that it is likely to have a hard time analyzing games by players at a higher level than 2d.
Out of curiosity, I tried runing sgf-analyze on a 9d game annotated by GoGameGuru. I ran 1 million simulations per move using the extra pattern files, and ran analyze-sgf once for black and once for white. The output of sgf-analyze looks something like this:
2, W, D16, C12, 0.52
... |
./sgf-analyze.pl game.sgf B -t =1000000 threads=4 -d 0 dynkomi=none > analysis-B./sgf-analyze.pl game.sgf W -t =1000000 threads=4 -d 0 dynkomi=none > analysis-Wtail -n +2 analysis-B | tr -d "," | awk '($3 == $4) {print $1, $5}' > B-agreetail -n +2 analysis-B | tr -d "," | awk '($3 != $4) {print $1, $5}' > B-disagreetail -n +2 analysis-W | tr -d "," | awk '($3 == $4) {print $1, 1 - $5}' > W-agreetail -n +2 analysis-W | tr -d "," | awk '($3 != $4) {print $1, 1 - $5}' > W-disagreexmgrace -nxy B-agree B-disagree W-agree W-disagree |
Like GNU Go, Pachi is only as good as its heuristic algorithm, and if it can't see as far ahead in the game as the professionals can, then the probability it predicts will not be illuminating. Indeed, comparing the GoGameGuru's notes on which moves were brilliant and which were mistakes to Pachi's did not yield any noticeable correlation. In fact, Pachi seemed to think that black resigned when he was in fact coming back!
![]() |
| Figure 6: Pachi analysis of Junghwan vs. Yue. Major predicted turning points in the game are noted. For instance, from moves 123 to about 182, white was pulling ahead. After move 182, black was coming back in the game according to Pachi, but resigned at the end of move 238. Compare this to the analysis given at GoGameGuru. Pachi was run with 1 million simulations per move and using the extra pattern files. |
This analysis may have raised more questions than answers, but I did learn a few things about computer Go and human nature:
- No AI can transcend its heuristics. The AI will relentlessly play the move it sees as most profitable at every turn, whereas human players who know they are behind will tend to take a gamble to try to get back into the game, then resign if it fails.
- Whether or not there are diminishing returns in Go depends on your definition of value: if you consider value as the number of points secured per move, then the first dozen moves of the game are worth about 10 points apiece, and any move after the 200th is worth perhaps one. If you consider the value of a move as whether or not you can win the game with it, that could happen at any time.
- Komi does not appear in the plot of diminishing returns. While all games tend to fall within a few points of the value curve, no game is composed entirely of average moves.
Thanks to Andrew Jackson and Chris Gaiteri for illuminating conversations on this topic!
Tuesday, October 29, 2013
The Rescue Mission
The recent US Government Shutdown came at great expense to the American people. One of the side effects was that our national parks were shut down for two and a half weeks. Ordinarily this is merely an inconvenience, but in my case it was a serious problem: the Sunrise area closes on October 15, and the shutdown meant that my pinhole cameras would be irretrievable until next Summer.
... or would they be? Benson suggested that we could boldly hike up from the White River campground and rescue the cameras in an epic 9-mile, 2500-ft elevation change day hike. And so the rescue plan was born. Remarkably, all of my cameras were still intact and where I left them and had not been found by curious or vigilant hikers. A few of the results came out looking great, but I learned a few more lessons:
... or would they be? Benson suggested that we could boldly hike up from the White River campground and rescue the cameras in an epic 9-mile, 2500-ft elevation change day hike. And so the rescue plan was born. Remarkably, all of my cameras were still intact and where I left them and had not been found by curious or vigilant hikers. A few of the results came out looking great, but I learned a few more lessons:
- The pinhole really should be as small as possible for a sharp image. If a camera is to be left out for months or longer, a very small sewing pin will suffice.
- If the can is mounted vertically, then the pinhole should be on the cylindrical edge of the can and near the top of the can as it is mounted.

The pinhole should be near the top of the can assuming the can is mounted vertically. - Ideally, a subject should either have extreme color variation, be shiny, or be partially transparent. The shadow of the subject should hit the can directly for part of the day.
Here are the successful photos:
![]() |
| Taken from the base of a tree on the Sourdough Ridge trail, exposed June 30-Oct 26 2013. |
![]() |
| Camera from a dead tree on a rock outcropping. Exposed June 30-Oct 26 2013, |
![]() |
| Taken from behind a stump. Exposed June 30-Oct 26 2013. |
Thanks to Benson for challenging Simiao and I to undertake this daring rescue. He took some photos of his own that you might enjoy.
| Mission successful! |
Wednesday, October 23, 2013
I Am Now Engaged
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You wouldn't have known that from how nervous I felt going in. When I was on my way to the airport to pick her up, and when I was driving up to The Inn on Orcas Island for our weekend getaway, I couldn't drive at a constant speed because my feet were shaking nervously. I didn't sleep at all the night before, and if I did start to doze, I had nervous dreams like this one:
![]() |
| An actual dream I had the night before I proposed to Simiao. Proof that my imagination hates me. |
| What I intended to say. | What was actually said. |
|---|---|
| Simiao, do you remember what I said I wanted from a relationship when we first met? I said I wanted compromise, patience, and reciprocity. You gave me all of those things. On top of that, you are generous, brilliant, hardworking honest, loving, adventurous, and every day you challenge me to be a better person and a better partner. I love you, and if you feel the same way, then will you marry me? | Sweetheart, don't cry yet, I haven't even started! Simiao, do you remember what I said I wanted from a relationship when we first met?I said I wanted compromise, patience, and reciprocity. [Hug break] You gave me all of those things. On top of that you are generous, brilliant, ... and a bunch of other things I can't remember right now because I'm so nervous... every day you challenge me to be a better person and a better partner. I love you, and if you feel the same way, then will you marry me? |
Thankfully, she forgave me for forgetting my lines and said "Yes" anyway.
Actually, I think the hardest part of the road to engagement was coming to a better understanding of love. A long time ago I was at a friend's bachelor party and he was having a conversation with a much, much older gentleman. The older gentleman was talking about how lucky my friend was to be in love his fiancee. The older gentleman related that he had never actually loved his wife who he had been with for decades and with whom he had several children. The possibility that this could actually happen to a person was terrifying to me, and because of this I spent years carefully examining every romantic relationship I had: Do I actually love this person? How do I know if I actually love this person? What if this feeling isn't actually love? What if I love someone else more? How do you even compare that? This is a fruitless line of thought.
![]() |
| The table where I proposed to Simiao. The best thing about this table was that since I was facing away from the rest of the room, I didn't have to see their eyes on me. |
I've heard it said that people spend a lifetime looking for the feeling they get the first time they fall in love. I've come to believe that this is indeed true. People also spend a lifetime looking for the feeling they get the second time, the third, the fourth, et cetera. I have learned that every person you ever love, be it your parents, your brother, your best friend, or a romantic interest, you will love in a different, unique and irreplaceable way. Thankfully, loving one person romantically isn't mutually exclusive with loving any number of people Platonically. Your family will still be there, your friends will still be there, and your partner will understand that it is not necessary or desirable that you should share every single hobby and interest and that these other people are an essential part of your life as well. This simple realization quieted my concerns about whether the way I felt about Simiao was right and let me instead focus on why, as I should have been all along.
Thursday, September 5, 2013
Why is Platinum More Expensive than Gold?
During a discussion at dinner today, I asked a question that seems silly and naive: why is platinum more expensive than gold? The answer, I think, is interesting and surprisingly complicated.
I read an article recently that said that the majority of the universe's gold and platinum originates from neutron star collisions, and in fact that 7 to 10 times more platinum comes from these collisions than gold. Figure 1 shows a reproduced and modified figure from the article where they show the expected mass fraction ejected of a variety of atomic mass numbers. It's noteworthy that gold is stable only at mass number 197, whereas platinum is stable at mass numbers 194, 195 and 196. Roughly 1/3 of the platinum around today is atomic mass 194, 1/3 is 195, about 1/4 is 196, and most of the rest is atomic mass 198.
If we assume that all of the ejecta at each mass number ends up being the corresponding element, then summing the mass fractions for platinum 194, 195, 196 and 198 in figure 1 we see that the mass fraction of platinum ejected from the collision of two neutron stars is about 0.015, and the mass fraction of gold ejected is 0.002. That means that about 7.5 times more platinum coming out of our collision than gold.
Now our chunks of platinum and gold hurtle out of a gravity wave inducing neutron star collision into space and eventually land in our solar system in the form of meteors. There's no reason to believe that platinum and gold have separated out significantly on their way to Earth since the abundance of these elements on Earth are 1.9 micrograms/gram for platinum and 0.16 micrograms/gram for gold--so there is roughly 11.8 times more platinum than gold in our planet as a whole by mass.
However, the platinum in the core and the mantle is all but inaccessible to us. The abundance of platinum and gold in the crust on the other hand is roughly equal at 0.0037 parts per million for platinum and 0.0031 parts per million for gold. It is still not worth mining either unless some natural process concentrates it, and it seems that there must be fewer such natural processes that lead to the concentration of platinum since only 179 tons of platinum were mined in 2012 compared to 2,700 tons of gold. For instance, gold deposits form at fault lines when rapid pressure changes during earthquakes cause dissolved gold to precipitate from water underground. I could not find any articles on natural mechanisms for concentration of platinum.
Finally, there is human history working in favor of gold. Gold has been known and collected for as long as recorded history, whereas platinum was only recently discovered in the mid-1750s. Nearly all of the gold that humans have ever collected is still with us in one form or another, and it is estimated that all of the gold that humans have ever possessed equals about 283,000 metric tons, compared to only about 6,000 metric tons of platinum.
So, thanks to geology and human history, we have gone from platinum being 7.5 times more common than gold in neutron star collisions to being substantially scarcer than gold in our possession. Without considering global demand, it's still fair to say this scarcity in supply is why platinum is more expensive than gold.
I read an article recently that said that the majority of the universe's gold and platinum originates from neutron star collisions, and in fact that 7 to 10 times more platinum comes from these collisions than gold. Figure 1 shows a reproduced and modified figure from the article where they show the expected mass fraction ejected of a variety of atomic mass numbers. It's noteworthy that gold is stable only at mass number 197, whereas platinum is stable at mass numbers 194, 195 and 196. Roughly 1/3 of the platinum around today is atomic mass 194, 1/3 is 195, about 1/4 is 196, and most of the rest is atomic mass 198.
![]() |
| Figure 1: Adapted from Goreily et. al. (2011). Mass fractions of heavy elements ejected from neutron star collisions. This is believed to be the major source of heavy elements in the universe. |
Now our chunks of platinum and gold hurtle out of a gravity wave inducing neutron star collision into space and eventually land in our solar system in the form of meteors. There's no reason to believe that platinum and gold have separated out significantly on their way to Earth since the abundance of these elements on Earth are 1.9 micrograms/gram for platinum and 0.16 micrograms/gram for gold--so there is roughly 11.8 times more platinum than gold in our planet as a whole by mass.
However, the platinum in the core and the mantle is all but inaccessible to us. The abundance of platinum and gold in the crust on the other hand is roughly equal at 0.0037 parts per million for platinum and 0.0031 parts per million for gold. It is still not worth mining either unless some natural process concentrates it, and it seems that there must be fewer such natural processes that lead to the concentration of platinum since only 179 tons of platinum were mined in 2012 compared to 2,700 tons of gold. For instance, gold deposits form at fault lines when rapid pressure changes during earthquakes cause dissolved gold to precipitate from water underground. I could not find any articles on natural mechanisms for concentration of platinum.
Finally, there is human history working in favor of gold. Gold has been known and collected for as long as recorded history, whereas platinum was only recently discovered in the mid-1750s. Nearly all of the gold that humans have ever collected is still with us in one form or another, and it is estimated that all of the gold that humans have ever possessed equals about 283,000 metric tons, compared to only about 6,000 metric tons of platinum.
So, thanks to geology and human history, we have gone from platinum being 7.5 times more common than gold in neutron star collisions to being substantially scarcer than gold in our possession. Without considering global demand, it's still fair to say this scarcity in supply is why platinum is more expensive than gold.
Saturday, August 3, 2013
Folding Kinetics of Riboswitch Transcriptional Terminators and Sequesterers
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| A golden buprestid found near Port Angeles sparkles like an exotic jewel. |
A riboswitch is a piece of RNA that serves both as a detector of some kinds of molecules and a switch to turn a gene's expression on and off. For example, bacteria might be able to consume a certain kind of nutrient. If the nutrient was found in the bacteria's environment, it would turn on a gene to make some proteins that can metabolize the nutrient. The bacteria could use a riboswitch to sense the nutrient and to turn on the gene to digest it.
Some riboswitches work at the time of gene transcription, and work by stopping the RNA polymerase from completing the messenger RNA. This process is called transcriptional termination. Obviously, these riboswitches must perform their task quickly, because the RNA polymerase is able to make a gene on the timescale of seconds.
Other riboswitches work at the time of gene translation, and work by preventing a ribosome from binding to the messenger RNA and making the related protein. We call these sequesterers. The messenger RNA can be present in the cytoplasm for minutes or hours, so these riboswitches have a much longer timescale on which they may perform their task.
All riboswitches, like proteins, must fold into a particular shape in order to perform their tasks.
Using the open-source ViennaRNA software package, we simulated the folding of thiamine pyrophosphate riboswitches that use either the mechanism of transcriptional termination or sequestration to control their related genes and study the time it takes each type of riboswitch to fold into its functional shape. We find evidence that the transcriptional terminators, which must operate on a faster timescale than sequesterers, are naturally selected to fold more efficiently.
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